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If you could, would you produce Hydrogen from solar cells and water in your home for your own car?
It takes pure water for electrolysis. Bottled or purified.
Should be done only when there is surplus energy, at off-peak hours.
No, because it requires a lot of energy to extract hydrogen via electrolysis. Off peak hours are at night, when there's no Sun to provide power to a solar cell. Additionally, Solar Power technology is currently not very efficient, so you couldn't get much hydrogen from the process.
On top of that, you'd need a way to get the hydrogen from your house to your car, and a car that can burn hydrogen as fuel.
It's an interesting idea, but simply not feasible.